Deactivation Routes in Gold(I) Polypyridyl Complexes: Internal Conversion Vs Fast Intersystem Crossing
نویسندگان
چکیده
منابع مشابه
Thioxanthone in apolar solvents: ultrafast internal conversion precedes fast intersystem crossing.
The photophysics of thioxanthone dissolved in cyclohexane was studied by femtosecond fluorescence and transient absorption spectroscopy. From these experiments two time constants of ∼400 fs and ∼4 ps were retrieved. With the aid of quantum chemically computed spectral signatures and rate constants for intersystem crossing, the time constants were assigned to the underlying processes. Ultrafast ...
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The experimental ultrafast photophysics of thioxanthone in several aprotic organic solvents at room temperature is presented, measured using femtosecond transient absorption together with high-level ab initio CASPT2 calculations of the singlet- and triplet-state manifolds in the gas phase, including computed state minima and conical intersections, transition energies, oscillator strengths, and ...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2018
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.8b01993